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Correlation between chromium physicochemical properties in silicate melts and the corrosion behavior of chromia-forming alloy
Eric Schmucker, Carine Petitjean, Pierre-Jean Panteix, Laure Martinelli, Sabah Ben Lagha, Michel Vilasi

Correlation between chromium physicochemical properties in silicate melts and the corrosion behavior of chromia-forming alloy

Science & Mathematics Published 2018 Verification Pending

Overview & Synopsis

The relationship between the corrosion behavior of a Ni-30Cr alloy and the physicochemical properties of chromium in silicate and borosilicate melts at 1150 C has been investigated. Three glass compositions have been chosen in order to identify the effect of basicity and viscosity. The chromium solubility limits in borosilicate melts have been determined and compared with the basicity of the melts. The chromium diffusion coefficients in the melts have been determined with the square-wave voltammetry method. A strong impact of the melt viscosity has been found on the corrosion behavior of the Ni-30Cr alloy. This dependency indicates a mechanism involving a diffusion-limited process for the dissolution of the oxide.

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Document Information

Document Title Correlation between chromium physicochemical properties in silicate melts and the corrosion behavior of chromia-forming alloy
Author / Organization Eric Schmucker, Carine Petitjean, Pierre-Jean Panteix, Laure Martinelli, Sabah Ben Lagha, Michel Vilasi
Subject & Discipline Multidisciplinary Academic Open Research
Categories Science & Mathematics
Publication Year 2018
License / Rights Open Access / Creative Commons
Resource Verification Listed PDF (Verification Pending)
Original Host Website HAL Open Science (hal.science)
File Format application/pdf (Portable Document Format)
Language EN
Catalog ID DOC-37430
Original Source Link Visit Source Page on hal.science »