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Study of molecular spin-crossover complex Fe(phen)2(NCS)2 thin films
Shengwei Shi, G. Schmerber, J. Arabski, J.-B. Beaufrand, D. J. Kim, S. Boukari, M. Bowen, N. T. Kemp, N. Viart, G. Rogez, E. Beaurepaire, H. Aubriet, J. Petersen, C. Becker, D. Ruch

Study of molecular spin-crossover complex Fe(phen)2(NCS)2 thin films

Science & Mathematics Published 2009 Verification Pending

Overview & Synopsis

We report on the growth by evaporation under high vacuum of high-quality thin films of Fe(phen)2(NCS)2 (phen=1,10-phenanthroline) that maintain the expected electronic structure down to a thickness of 10 nm and that exhibit a temperature-driven spin transition. We have investigated the current-voltage characteristics of a device based on such films. From the space charge-limited current regime, we deduce a mobility of 6.5x10-6 cm2/V∙s that is similar to the low-range mobility measured on the widely studied tris(8-hydroxyquinoline)aluminium organic semiconductor. This work paves the way for multifunctional molecular devices based on spin-crossover complexes.

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Document Information

Document Title Study of molecular spin-crossover complex Fe(phen)2(NCS)2 thin films
Author / Organization Shengwei Shi, G. Schmerber, J. Arabski, J.-B. Beaufrand, D. J. Kim, S. Boukari, M. Bowen, N. T. Kemp, N. Viart, G. Rogez, E. Beaurepaire, H. Aubriet, J. Petersen, C. Becker, D. Ruch
Subject & Discipline Multidisciplinary Academic Open Research
Categories Science & Mathematics
Publication Year 2009
License / Rights Open Access / Creative Commons
Resource Verification Listed PDF (Verification Pending)
Original Host Website HAL Open Science (hal.science)
File Format application/pdf (Portable Document Format)
Language EN
Catalog ID DOC-236062
Original Source Link Visit Source Page on hal.science »