Natural isotopic abundance $^{13}$C and $^{15}$N multidimensional solid-state NMR enabled by dynamic nuclear polarization
Overview & Synopsis
Dynamic nuclear polarization (DNP) has made feasible solid-state NMR experiments that were previously thought impractical due to sensitivity limitations. One such class of experiments is the structural characterization of organic and biological samples at natural isotopic abundance (NA). Herein, we describe the many advantages of DNP-enabled ssNMR at NA, including the extraction of long-range distance constraints using dipolar recoupling pulse sequences without the deleterious effects of dipolar truncation. In addition to the theoretical underpinnings in the analysis of these types of experiments, numerous applications of DNPenabled ssNMR at NA are discussed.
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Document Information
| Document Title | Natural isotopic abundance $^{13}$C and $^{15}$N multidimensional solid-state NMR enabled by dynamic nuclear polarization |
|---|---|
| Author / Organization | Adam Smith, Katharina Märker, Sabine Hediger, Gaël de Paëpe |
| Subject & Discipline | Multidisciplinary Academic Open Research |
| Categories | Science & Mathematics |
| Publication Year | 2019 |
| License / Rights | Open Access / Creative Commons |
| Resource Verification | Listed PDF (Verification Pending) |
| Original Host Website |
HAL Open Science
(hal.science)
|
| File Format | application/pdf (Portable Document Format) |
| Language | EN |
| Catalog ID | DOC-229240 |
| Original Source Link | Visit Source Page on hal.science » |