First lipase catalysed resolution of epoxy enol esters.
Overview & Synopsis
We report the first enzyme-catalysed kinetic resolution of epoxy enol esters. The lipase-promoted hydrolysis of these compounds provided α-hydroxyketones or α-hydroxyaldehydes (arising from the spontaneous rearrangement of the epoxy enols) and the residual esters with moderate to good enantioselectivity (E up to 100).
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Document Information
| Document Title | First lipase catalysed resolution of epoxy enol esters. |
|---|---|
| Author / Organization | Sébastien Gravil, H. Veschambre, Robert Chenevert, Jean Bolte |
| Subject & Discipline | Multidisciplinary Academic Open Research |
| Categories | Science & Mathematics |
| Publication Year | 2006 |
| License / Rights | Open Access / Creative Commons |
| Resource Verification | Listed PDF (Verification Pending) |
| Original Host Website |
HAL Open Science
(hal.science)
|
| File Format | application/pdf (Portable Document Format) |
| Language | EN |
| Catalog ID | DOC-224759 |
| Original Source Link | Visit Source Page on hal.science » |