Diverging Pathways to Topologically Complex Polycyclic Bis-acetals and Their Ring System Interchange
Overview & Synopsis
Carbinol-tethered octalin-diols, which differ only by the C11 configuration at the angular position, were transformed selectively to three types of structurally unrelated original scaffolds such as unsymmetrical octahydroanthracenes, furofuranes or spirans via a two-step protocol. The 11S* configuration ensures a C13–C4 Friedel–Crafts type C–C bonding (through an unprecedented oxidative cleavage-triggered domino process) while the 11R* configuration allows for a C13–C2 Marson-type Friedel–Crafts C–C bonding (through a nucleophilic acetal opening).
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Document Information
| Document Title | Diverging Pathways to Topologically Complex Polycyclic Bis-acetals and Their Ring System Interchange |
|---|---|
| Author / Organization | Castillo, Rafael, Aquino, Maurizio, Gándara, Zoila, Safir, Imad, Elkhayat, Zobida, Retailleau, Pascal, Arseniyadis, Siméon |
| Subject & Discipline | Scientific Research & Data |
| Categories | Science & Mathematics |
| Publication Year | 2012 |
| License / Rights | cc-by-4.0 |
| Resource Verification | Listed PDF (Verification Pending) |
| Original Host Website |
Zenodo
(zenodo.org)
|
| File Format | application/pdf (Portable Document Format) |
| Reported File Size | 1862 KB (1,906,737 bytes) |
| Language | EN |
| Catalog ID | DOC-19255 |
| Original Source Link | Visit Source Page on zenodo.org » |