Preparation and structure of the 17-electron (η5-C5R5)Mo(OH)2(dppe) (R=Me, Et) organometallic compounds containing two gem-terminal hydroxide ligands
Overview & Synopsis
Oxidation of (η5-C5R5)MoH3(dppe) (R=Me, Et) by Cp2Fe+ in wet THF leads to the formation of the corresponding (η5-C5R5)Mo(OH)2(dppe). These compounds show a low-potential reversible oxidation wave. The structure of the C5Et5 complex has been confirmed by X-ray diffraction methods: triclinic; space group ; a=11.030(1); b=12.533(1); c=16.241 (1) Å; α=68.585(7); β=75.197(5); γ=83.991(7)°; V=2020.6(3) Å3; Z=2; Dcalc=1.324 g cm−3, μ(Mo–Kα)=0.441 mm−1; R1=0.0325; wR2=0.0875 for 415 parameters and 6823 independent reflections [Rint=0.0177] with I=2σ(I). The molecule shows a four-legged piano-stool geometry with two terminal OH ligands in a relative trans configuration. The complex EPR properties indicate that an equilibrium mixture of various species is present in solution.
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| Document Title | Preparation and structure of the 17-electron (η5-C5R5)Mo(OH)2(dppe) (R=Me, Et) organometallic compounds containing two gem-terminal hydroxide ligands |
|---|---|
| Author / Organization | Dolores Morales, Brett Pleune, Rinaldo Poli, Philippe Richard |
| Subject & Discipline | Multidisciplinary Academic Open Research |
| Categories | Science & Mathematics |
| Publication Year | 2000 |
| License / Rights | Open Access / Creative Commons |
| Resource Verification | Listed PDF (Verification Pending) |
| Original Host Website |
HAL Open Science
(hal.science)
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| File Format | application/pdf (Portable Document Format) |
| Language | EN |
| Catalog ID | DOC-12343 |
| Original Source Link | Visit Source Page on hal.science » |