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The Prussian blue analogue RbxMn[Fe(CN)6](x+2)/3.zH2O (RbMnFe) is highly multifunctional. The RbMnFe compounds (0.6 ≤ x ≤ 1) can switch between High Temperature (HT, with Mn(II)-Fe(III) pairs) and Low Temperature (LT, wi...